Problem 1.1: We are tasked with determining the leakage rate in a pipeline containing toluene where the leak is a 0.20'' diameter hole
Specific gravity of toluene = 0.866
Using the Qm equation for liquids we can plug in our 100 psig (pressure at the point of leak) and 0.2'' diameter to solve for mass flow rate in lbm/s
Using two different discharge coefficients, we can solve for mass flow rate in the ideal case (C0 = 0.61), and in the worst case (C0 = 1.0)
Problem 1.2: We are tasked with determining the intitial mass flow rate of Nitrogen out of a cylindrical tank if it were to fall and shear off a valve.
Contains Nitrogen at 2200 psia
Hole diameter is 0.5''
Using the choked flow equation with a worst case C0 of 1 and plugging in the diameter and pressure, we can solve for the choked flow (Qm) in lbm/s
Problem 3.1: We are tasked with determining the diameter of spring-type liquid reliefs for the following conditions.
a) 100 gpm capacity at deltaP, 50 psig set pressure, 20% overpressure, 10% backpressure, conventional valve, p/pref = 1.0
b) 200 gpm capacity at deltaP, 100 psig set pressure, 20% overpressure, 30% backpressure, balanced bellows valve, p/pref = 1.3
c) 50 gpm capacity at deltaP, 50 psig set pressure, 10% overpressure, 40% backpressure, conventional valve, p/pref = 1.2
First we would calculate backpressure Pb by its percentage times the set pressure Ps
Assuming turbulent flow, all viscosity corrections (Kv) were set equal to 1
Backpressure and overpressure corrections (Kb and Kp, respectively) were obtained from % pressure vs K curves
The ideal C0 = 0.61 was used for all cases
Problem 11.1: Here we had to look at the PSM and RMP regulations to see if these chemicals are toxic or flammable and what their threshold quantities are.
PSM TQ's
Acrolein - 150 lbs
Propane - Not PSM regulated
Hydrogen Chloride - 5000 lbs
Ethylene Oxide - 5000 lbs
Phosgene - 100 lbs
Methanol - Not PSM regulated
RMP TQ's
Acrolein - 5000 lbs (toxic)
Propane - 1000 lbs (toxic)
Hydrogen Chloride - 5000 lbs (toxic)
Ethylene Oxide - 10,000 lbs (toxic)
Phosgene - 500 lbs (toxic)
Methanol - Not RMP regulated
PSM is regulated by OSHA and RMP by the EPA through the Clean AIr Act. PSM threshold quantities are lower than RMP because they deal with human toxicity whereas RMP deals with emissions and the atmosphere can handle things that our bodies cannot.
Common Design Project 11: In this part of the CDP, we had to explore environmental and safety concerns by looking at the Safety Data Sheets for the streams in the Aspirin precursor (Acetic Anhydride) production.
Streams that were focused on:
Inlet acetone
Outlet ketene
Outlet methane
Problem 2.1: We are tasked with determining the minimum wall thickness to store liquid chlorine in a cylindrical tank with hemispherical ends given the following.
Maximum allowable stress for material = 110 MN/m^2
Stored at 10 bar
4m internal diameter
20m long
Design pressure = 12 bar
We them calculate thickness required for each section for both hoop and longitudinal stress. Whichever thickness is higher and governs what thickness we will use in the design.
Hoop stress governs with a thickness t = 0.022m
Lastly, thickness for hemispherical ends is calculated to be 11mm.
Problem 2.2: We are tasked with determining the plate thickness at the base of a tank containing concentrated nitric acid constructed from aluminum, given the following.
Inside diameter = 6m
Height = 17m
Max liquid level level in tank - 16m
Aluminum design stress = 90 MN/m^2
Problem 6.1: We are tasked with sizing a drum to separate water droplets from air given that the inlet flow rate of air is 1000 m^3/h at STP, containing 75kg of water.
The water added to the air has virtually no bearing on the vapor flow rate versus the entire volumetric flow rate (1000 vs. 999.9)
Using the equation ut to calculate settling velocity is also equal to us, assuming there is a demister
The us can be used in the diameter equation for vertical separators along with the vapor volumetric flow rate
Then the liquid flow can be calculated with a simple conversion
Lastly, height can be calculated assuming a 10 minute hold-up by dividing the liquid volume flow by the corresponding cross sectional area
This gives us a diameter of 0.42m and a height of 0.09m
Problem 7.1: We are tasked with determining the most cost effective way to replace a failed Schedule 40 carbon steel pipe (O.D 114.3mm/4.5 in ID 102.3 mm/4.026 in) with an expected lifespan of 7 years using three different options:
Same steel pipe replaced every 3 years($5.00/unit)
Replace with Schedule 80 pipe ($8.30/unit)
Use stainless steel pipe ($24.80/unit)
Installation and fixings are $16.50/unit length.
Problem 8.1: Looking at a graph of natural gas prices over the past 15 years, we were tasked with predicting a rough sketch of the next 15 years with a brief explanation.
Problem 8.2: Estimate the cash cost of production for a company that produces 60,000 metric tons of Nylon 6 with an estimated fixed capital cost of $114MM.
Raw Materials:
Caprolactam: 1.02 metric tons/metric ton product: $1700/MT
Utilities:
Cooling Water: 32,000 gal/ton of product (need to estimate cost)
Electrical Power: 130 kWh/ton of product (need to estimate cost)
After inputting the fixed and variable costs in the excel sheet, I got an estimated cash cost of production at $1951.20/unit product.
All over the world, throughout many industries, companies and organizations have to deal with ethical, moral, and social dilemmas constantly. Obviously, they want to keep these at a minimum, but they should not be skipped over, for the safety of consumers is of the utmost importance. One company that deals with this a lot is Boeing. The majority of flights that we are on for our travels are Boeing Airplanes. With such a large consumer base, they are often held at the highest standard for safety. On June 18, 2021, a Boeing 787 Dreamliner jet flying for British Airways was parked on its stand at London Heathrow Airport where its nose struck the ground, causing significant damage. The lower front side of the fuselage was damaged, causing minor injuries to the co-pilot and a cargo loading crew member. This brings in the question of whether anything was neglected in safety protocol with an underlying ethical issue.
This flight was scheduled for a cargo departure to Frankfurt, Germany, so luckily there were not any unsuspecting tourists involved. The main issue was that, when the maintenance crew was working on addressing three fault codes for the nose landing gear, the Licensed Aircraft Engineer told the captain it would only take about forty minutes to resolve the issue. The captain did not see anything wrong during his walk-around, so the crew resumed loading freight onto the aircraft. When the First Officer received clearance for departure, the landing gear was raised to the up position which then crashed the nose into the ground.
Upon further inspection, the cause of the crash was deemed to be an incorrect pin placement. The nose landing gear downlock pin was found to be installed in the wrong place. They could not hear or see anything that would have led them to believe the pin was in the wrong place, though. The installation by the maintenance team is supposed to be guided by airworthiness standards; however, there was no documentation confirming that on this installation.
There are at least two ways this incident could have been avoided. One being preventative maintenance and two being further inspection and communication before attempted departure. When combining the ethical, moral, and societal shortcomings of just two different parties, problems are likely to arise, which is why we have to make sure everyone is on board with their standards. In the case of the maintenance, it seems like it would be easy to complete all the necessary preventative measures, but humans are bound to make some mistakes. Some may be overworked and not thinking clearly, some might be trying to rush in order to leave work early, and some might be morally naïve to what consequences a small fault may have, or they just may not care in which they should not be in a profession where safety is so important. On the other hand, it is not just the maintenance crew’s fault. Prior to loading cargo, the crew should have investigated the three fault codes until they found out what exactly was wrong with the aircraft. Why might they have skipped over this issue so quickly? This could be many things, including miscommunication, being in a rush, and profit incentives. Profit incentives seem to be one of the most common ethical issues across all industries. All of us want to make money, but that should come after guaranteeing the safety of our society. When flying a cargo airplane, or any plane for that matter, pilots have to stick to strict schedules. They were most likely due to deliver the cargo to Frankfurt at a certain time that they were trying to be on schedule for, which could have caused them to rush. Also, being able to consistently deliver to buyers will make you a credible supplier/distributor, and being late could mean costing the buyers more money and developing a lack of trust in their supplier. If the supplier were to lose their buyer’s trust, then they would be likely to lose money too. Overall, this particular Boeing incident is a good example of an engineering mishap that could be studied in order to see what was done and what could have been done to prevent future disasters.
References
Petrauskaite, Gabriele. “BA Boeing 787 Nose-Gear Incident Caused by Engineer Fault: AAIB.” AeroTime Hub, 4 Nov. 2022, https://www.aerotime.aero/articles/32566-ba-boeing-787-nose-gear-incident-caused-by-engineer-fault-aaib.
Many of us our familiar with Aspirin, which is more formally known as acetylsalicylic acid. It is produced by the reaction of salicylic acid with acetic anhydride where the acetic anhydride acetylates the salicylic acid. In our common design project, our focus was on production of the precursor, acetic anhydride. First, ketene (ethenone) and methane produced through the thermal decomposition of acetone. The ketene is then fed to an absorption tower and finally a distillation column, where the outlet is acetic anhydride. The part that brings up the potential ethical, moral, and societal dilemmas that we are going to be focusing on is the production of ketene before it becomes acetic anhydride.
For the thermal decomposition to occur, the reaction occurs in the gaseous phase at high temperatures and moderate pressures. Considering that the reaction is in the gaseous phase, one of the first safety concerns should be regulating pressure. Before we ship off the precursor and worry about the post-production consequences, we want to take the safety of our workers and plant into account. We want to make sure all of our plant workers understand how important the safety of this process is and that they are diligent about mitigation. A possible dilemma could be that a worker either was distracted and unaware of or saw something and failed to implement mitigation strategies. Our priority should be ensuring that pressure controllers, indicators, gages, etc. are working properly so that the reactor doesn’t blow up, jeopardizing the safety of everyone, and diminishing our output. In order to achieve our product in the safest manner, the reaction should be run at 700 degrees Celsius and 162 kPa while also restricting the conversion to 40%. When it comes to output, there’s likely to be some ethical issues that come about. Other than safety, one the plant’s top priorities is output. The more we produce, the more money we make, right? Well, if safety is jeopardized, revenue losses due to output would be the least of our worries. Let’s say someone new gets hired in a management position at the plant, and their primary goal is growing the company and maximizing profits. Someone needs to be there to draw the line at which more profit does not warrant pushing the boundaries of safety. This is why we need a collective group of ethically and morally responsible individuals at the company and why hiring should entail more than just “Can you get our output to where it needs to be, etc”.
Not only do we have to consider the immediate impacts of our plant, but there are also some down the road to consider too. The process of producing ketene has immediate standards for safety, but have we considered our outlet streams? Going back to the reaction, we see that methane is one of the products in the thermal decomposition reaction. Methane, a greenhouse gas, is a powerful contributor to climate change. Along with CO2, it amplifies the effects of carbon emissions. It may not seem like a pressing manner now, but we need to help do our part in reducing emissions too if we want the planet to be sustainable. To help out, we can minimize our methane emissions by reducing output, which in turn makes the process safer and less susceptible to explosion too. We can also consider capturing the methane, just as carbon capture technology is becoming a more well-known thing. From there, we can find ways to repurpose the methane instead of just dumping it into the atmosphere, and effectively warming the globe, causing sea levels to rise, etc. It is interesting to see how just in one step of pre-production of a useful drug, there are many things to consider from an ethical standpoint which opens up endless possibilities in which we can do our part to ensure the safety and well-being of society.
References
“Acetic Anhydride.” Chematur Engineering AB, 8 June 2015, https://chematur.se/technologies/bio-chemicals/acetic-anhydride/#:~:text=Acetic%20anhydride%20is%20produced%20from,with%20water%20at%20high%20temperature.